Realizing the ENERGY POTENTIAL of METHANE HYDRATE for the United States
NATIONAL RESEARCH COUNCIL
OF THE NATIONAL ACADEMIES
THE NATIONAL ACADEMIES PRESS
Washington, D.C.
www.nap.edu
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NOTICE: The project that is the subject of this report was approved by the Governing Board of the National Research Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of Engineering, and the Institute of Medicine. The members of the committee responsible for the report were chosen for their special competences and with regard for appropriate balance.
The opinions, findings, and conclusions or recommendations contained in this document are those of the authors and do not necessarily reflect the views of the U.S. Department of Energy. Mention of trade names or commercial products does not constitute their endorsement by the U.S. government. Supported by the Department of the Energy, under Award No. DE-AT01-08FE0053.
International Standard Book Number-13: 978-0-309-14889-4
International Standard Book Number-10: 0-309-14889-8
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Cover: The backdrop is a three-dimensional rendering of the “structure 1” or s1 methane hydrate in which methane molecules (represented by spheres) are trapped inside hydrogen-bonded water cages. The images embedded within the cages include a hand-held methane hydrate-bearing sediment sample from the Mt. Elbert well at Milne Point, Alaska (upper left), prepared drillcores from the Department of Energy/Joint Industry Project Gulf of Mexico methane hydrate cruise (middle), and the Doyon 14 drill rig at the Mount Elbert test site, Milne Point, Alaska (lower middle). Images courtesy of: M. R. Walsh, Colorado School of Mines (three-dimensional si methane hydrate structure); Mount Elbert Gas Hydrate Research Team (both the Mt. Elbert hand-held core sample and drill rig); Gulf of Mexico Department of Energy/ Joint Industry Project Research Team (prepared drill cores).
Designed by Michael Dudzik.
Copyright 2010 by the National Academy of Sciences. All rights reserved.
Printed in the United States of America.
THE NATIONAL ACADEMIES
Advisers to the Nation on Science, Engineering, and Medicine
The National Academy of Sciences is a private, nonprofit, self-perpetuating society of distinguished scholars engaged in scientific and engineering research, dedicated to the furtherance of science and technology and to their use for the general welfare. Upon the authority of the charter granted to it by the Congress in 1863, the Academy has a mandate that requires it to advise the federal government on scientific and technical matters. Dr. Ralph J. Cicerone is president of the National Academy of Sciences.
The National Academy of Engineering was established in 1964, under the charter of the National Academy of Sciences, as a parallel organization of outstanding engineers. It is autonomous in its administration and in the selection of its members, sharing with the National Academy of Sciences the responsibility for advising the federal government. The National Academy of Engineering also sponsors engineering programs aimed at meeting national needs, encourages education and research, and recognizes the superior achievements of engineers. Dr. Charles M. Vest is president of the National Academy of Engineering.
The Institute of Medicine was established in 1970 by the National Academy of Sciences to secure the services of eminent members of appropriate professions in the examination of policy matters pertaining to the health of the public. The Institute acts under the responsibility given to the National Academy of Sciences by its congressional charter to be an adviser to the federal government and, upon its own initiative, to identify issues of medical care, research, and education. Dr. Harvey V. Fineberg is president of the Institute of Medicine.
The National Research Council was organized by the National Academy of Sciences in 1916 to associate the broad community of science and technology with the Academy’s purposes of furthering knowledge and advising the federal government. Functioning in accordance with general policies determined by the Academy, the Council has become the principal operating agency of both the National Academy of Sciences and the National Academy of Engineering in providing services to the government, the public, and the scientific and engineering communities. The Council is administered jointly by both Academies and the Institute of Medicine. Dr. Ralph J. Cicerone and Dr. Charles M. Vest are chair and vice chair, respectively, of the National Research Council.
COMMITTEE ON ASSESSMENT OF THE DEPARTMENT OF ENERGY’S METHANE HYDRATE RESEARCH AND DEVELOPMENT PROGRAM: EVALUATING METHANE HYDRATE AS A FUTURE ENERGY RESOURCE
CHARLES PAULL (Chair1),
Monterey Bay Aquarium Research Institute, Moss Landing, California
WILLIAM S. REEBURGH (Chair2),
University of California, Irvine (Retired)
SCOTT R. DALLIMORE,
Geological Survey of Canada, Sidney, British Columbia
GONZALO ENCISO, Oil and Gas Exploration Consultant,3
Houston, Texas
SIDNEY GREEN,
University of Utah, Salt Lake City
CAROLYN A. KOH,
Colorado School of Mines, Golden
KEITH A. KVENVOLDEN,
U.S. Geological Survey (Retired), Palo Alto, California
CHARLES MANKIN,
Oklahoma Geological Survey (Retired), Norman
MICHAEL RIEDEL,
Geological Survey of Canada, Sidney, British Columbia4
National Research Council Staff
ELIZABETH A. EIDE, Study Director
DEBORAH GLICKSON, Program Officer
NICHOLAS D. ROGERS, Financial and Research Associate
COURTNEY R. GIBBS, Program Associate
COMMITTEE ON EARTH RESOURCES
CLAYTON R. NICHOLS (Chair1),
Department of Energy, Idaho
Operations Office (Retired),
Ocean Park, Washington
MURRAY W. HITZMAN (Chair2),
Colorado School of Mines, Golden
JAMES A. BRIERLEY,
Brierley Consultancy LLC, Highlands Ranch, Colorado
WILLIAM S. CONDIT, Independent Consultant,
Santa Fe, New Mexico
ELAINE T. CULLEN,
National Institute of Occupational Safety and Health, Spokane Research Laboratory (Retired), Chattaroy, Washington
GONZALO ENCISO, Oil and Gas Exploration Consultant,
Houston, Texas
MICHELLE MICHOT FOSS,
University of Texas, Austin
DONALD JUCKETT,
American Association for Petroleum Geologists (Retired), Springfield, Virginia
ANN S. MAEST,
Stratus Consulting, Boulder, Colorado
LELAND L. MINK,
U.S. Department of Energy Geothermal Program (Retired), Worley, Idaho
MARY M. POULTON,
University of Arizona, Tucson
NORMAN H. SLEEP,
Stanford University, Stanford, California
RICHARD J. SWEIGARD,
University of Kentucky, Lexington
SAMUEL J. TRAINA,
University of California, Merced
National Research Council Staff
ELIZABETH A. EIDE, Senior Program Officer
ERIC J. EDKIN, Senior Program Assistant
NICHOLAS D. ROGERS, Financial and Research Associate
BOARD ON EARTH SCIENCES AND RESOURCES
CORALE L. BRIERLEY (Chair),
Brierley Consultancy, LLC, Highlands Ranch, Colorado
KEITH C. CLARKE,
University of California, Santa Barbara
DAVID J. COWEN,
University of South Carolina, Columbia
WILLIAM E. DIETRICH,
University of California, Berkeley
ROGER M. DOWNS,
Pennsylvania State University, University Park
JEFF DOZIER,
University of California, Santa Barbara
KATHERINE H. FREEMAN,
Pennsylvania State University, University Park
WILLIAM L. GRAF,
University of South Carolina, Columbia
RUSSELL J. HEMLEY,
Carnegie Institution of Washington, Washington, D.C.
MURRAY W. HITZMAN,
Colorado School of Mines, Golden
EDWARD KAVAZANJIAN, JR.,
Arizona State University, Tempe
LOUISE H. KELLOGG,
University of California, Davis
ROBERT B. MCMASTER,
University of Minnesota, Minneapolis
CLAUDIA INÉS MORA,
Los Alamos National Laboratory, New Mexico
BRIJ M. MOUDGIL,
University of Florida, Gainesville
CLAYTON R. NICHOLS,
Department of Energy, Idaho Operations Office (Retired), Ocean Park, Washington
JOAQUIN RUIZ,
University of Arizona, Tucson
PETER M. SHEARER,
University of California, San Diego
REGINAL SPILLER,
Allied Energy, Houston, Texas
RUSSELL E. STANDS-OVER-BULL,
Anadarko Petroleum Corporation, Denver, Colorado
TERRY C. WALLACE, JR.,
Los Alamos National Laboratory, New Mexico
HERMAN B. ZIMMERMAN,
National Science Foundation (Retired), Portland, Oregon
National Research Council Staff
ANTHONY R. DE SOUZA, Director
ELIZABETH A. EIDE, Senior Program Officer
DAVID A. FEARY, Senior Program Officer
ANNE M. LINN, Senior Program Officer
SAMMANTHA L. MAGSINO, Program Officer
MARK D. LANGE, Associate Program Officer
LEA A. SHANLEY, Postdoctoral Fellow
JENNIFER T. ESTEP, Financial and Administrative Associate
NICHOLAS D. ROGERS, Financial and Research Associate
COURTNEY R. GIBBS, Program Associate
JASON R. ORTEGO, Research Associate
ERIC J. EDKIN, Senior Program Assistant
TONYA E. FONG YEE, Senior Program Assistant
OCEAN STUDIES BOARD
DONALD F. BOESCH (Chair),
University of Maryland Center for Environmental Science, Cambridge
EDWARD A. BOYLE,
Massachusetts Institute of Technology
JORGE E. CORREDOR,
University of Puerto Rico, Mayagüez
KEITH R. CRIDDLE,
University of Alaska Fairbanks, Juneau
JODY W. DEMING,
University of Washington
MARY (MISSY) H. FEELEY,
ExxonMobil Exploration Company, Houston, Texas
ROBERT HALLBERG,
National Oceanographic and Atmospheric Administration
DEBRA HERNANDEZ,
Hernandez and Company, Isle of Palms, South Carolina
ROBERT A. HOLMAN,
Oregon State University, Corvallis
KIHO KIM,
American University, Washington, D.C.
BARBARA A. KNUTH,
Cornell University, Ithaca, New York
ROBERT A. LAWSON,
Science Applications International Corporation, San Diego, California
GEORGE I. MATSUMOTO,
Monterey Bay Aquarium Research Institute, Moss Landing, California
JAY S. PEARLMAN,
The Boeing Company, Port Angeles, Washington
ANDREW A. ROSENBERG,
University of New Hampshire, Durham
DANIEL L. RUDNICK,
Scripps Institution of Oceanography, La Jolla, California
ROBERT J. SERAFIN,
National Center for Atmospheric Research, Boulder, Colorado
ANNE M. TREHU,
Oregon State University, Corvallis
PETER L. TYACK,
Woods Hole Oceanographic Institution, Massachusetts
DAWN J. WRIGHT,
Oregon State University, Corvallis
JAMES A. YODER,
Woods Hole Oceanographic Institution, Massachusetts
National Research Council Staff
SUSAN ROBERTS, Director
CLAUDIA MENGELT, Senior Program Officer
DEBORAH GLICKSON, Program Officer
JODI BOSTROM, Associate Program Officer
SHUBHA BANSKOTA, Financial Associate
PAMELA LEWIS, Administrative Coordinator
HEATHER CHIARELLO, Senior Program Assistant
JEREMY JUSTICE, Senior Program Assistant
Preface
The United States is at an important juncture as it considers future, long-term directions for supplying its own energy needs while also reducing the impact on the global environment. Consideration of the greenhouse gas contribution to the atmosphere of each energy source relative to its energy efficiency is a key part of this discussion. Natural gas, and particularly methane, because of its relatively clean environmental footprint—when combusted, natural gas produces less carbon dioxide per energy unit than do other fossil fuels—has emerged as a central piece in planning and implementing the nation’s transition to a future with cleaner, more efficient energy use. Whereas the current estimates of the nation’s undiscovered, conventional natural gas endowment on- and offshore are fairly substantial, the extent and accessibility of alternative sources of natural gas from “unconventional” (more technically challenging) sources are of increasing interest to policy makers, industry, and the public.
Methane hydrate, a solid form of methane and water that is widespread in Arctic permafrost areas of the Alaska North Slope and along most of the U.S. offshore continental margins, is an unconventional source of a potentially enormous volume of methane. Although the scientific, engineering, and environmental questions associated with exploration and potential commercial production of methane from methane hydrate are challenging, research programs around the world, including the United States, have made recent, substantial progress in understanding the behavior and extent of the resource and in performing drilling and production tests to extract methane from it. The results of these research endeavors provide the input to gauge the next steps toward realizing sustained, economically and environmentally viable production of methane from methane hydrate. The coming decade will prove pivotal as various nations attempt to make the transition from successful basic research and development programs to full-scale production of methane from methane hydrate in commercially
supported operations. The United States is one of the international leaders in this field by virtue of the excellence of the research its scientists have conducted and the rich natural endowment of methane hydrate offshore and associated with permafrost in Alaska. Our challenge is to realize this resource in a safe and environmentally sound manner.
In 2005, Congress reauthorized the Methane Hydrate Research and Development Program, initially established in the Methane Hydrate Research and Development Act of 2000 (Appendix A), focused on stimulating advancements in the understanding of methane hydrate. The Program’s goals involve generating the needed scientific and technical knowledge to produce methane from methane hydrate as an energy resource in an environmentally sound manner. The Department of Energy, in cooperation with the National Energy Technology Laboratory, has managed this Program through support to about 40 new and continuing projects between fiscal years 2006 and 2009. These projects range in size and scale from large field programs involving multiple institutions focused on drilling into methane hydrate deposits, to single-institution laboratory and modeling studies.
The Act also mandates that a National Research Council (NRC) study be conducted to evaluate the progress that the Program is making toward achieving its goals and to make recommendations about future research and development needs. This report is the product of a committee convened by the NRC for this purpose. The members of this review committee represent a range of expertise including geochemistry, geology, oceanography, geophysics, petroleum engineering, risk assessment, and chemical engineering from industry, academia, government, and nonprofit research foundations (Appendix B). The committee met as a whole four times (twice each in Washington, D.C., and Golden, Colorado) to hear invited presentations and review available materials associated with the Program (Appendix C).
In this report, the committee has tried to provide an overview for the interested nonspecialist on the present state of knowledge in this field, an assessment of the impact the Program has made on the field, and recommendations as to what the technical emphasis of the continuing program
ought to be over the next several years. The committee has made these recommendations in the context of a long-term goal for the Program and for many in the U.S. methane hydrate research community: to contribute research appropriate toward demonstration of environmentally and economically sustainable production of methane from methane hydrate by 2025. The committee realizes, however, that other factors, including regulatory issues and market economics, will also affect the ability of and timing for the nation to achieve this production aim. Overall, the committee has been impressed with both the quality of the work the Program has enabled and the progress that has been made toward this long-term goal. The committee’s research and development recommendations are thus intentionally high level, but specific with respect to the kind of technical and scientific emphasis we think necessary for the nation to attain this goal.
Charlie Paull
Chair
Acknowledgments
In addition to its own expertise, the committee relied on input from numerous external professionals with extensive experience in various aspects of methane hydrate research. These individuals provided presentations, data, perspectives, and illustrative figures and images which assisted the committee in understanding the scope of domestic and international research in the field and the role played by the Department of Energy Methane Hydrate Research and Development Program and other federal agencies to advance the field. This information was extremely important to the committee in formulating its report, and we would like to express our appreciation to the many highly qualified individuals who provided advice and assistance during the course of the study. In particular, the committee would like to thank the following individuals for their very thorough and helpful responses to our inquiries at all stages of the study: Edith Allison, Ray Boswell, Rick Coffin, Tim Collett, Helen Farrell, Robert Fisk, Matt Frye, Bob Hardage, James Howard, Robert Hunter, Emrys Jones, Tim Kneafsey, Debbie Hutchinson, Yoshihiro Masuda, Ian MacDonald, Kenji Ohno, Brenda Pierce, Kimberly Puglise, Kelly Rose, Carolyn Ruppel, Carlos Santamarina, Dendy Sloan, Bob Swenson, and Scott Wilson.
This report has been reviewed in draft form by individuals chosen for their diverse perspectives and technical expertise, in accordance with procedures approved by the NRC’s Report Review Committee. The purpose of this independent review is to provide candid and critical comments that will assist the institution in making its published report as sound as possible and to ensure that the report meets institutional standards for objectivity, evidence, and responsiveness to the study charge. The review comments and draft manuscript remain confidential to protect the integrity of the deliberative process. We wish to thank the following individuals for their participation in the review of this report:
Amos A. Avidan, Bechtel Corporation, Houston, Texas
Nathan L.B. Bangs, University of Texas, Austin
Inez Y. Fung, University of California, Berkeley
Steven H. Hancock, RPS Energy Canada, Calgary, Alberta
Kenneth C. Janda, University of California, Irvine
Joel E. Johnson, University of New Hampshire, Durham
Salomon Levy, Levy & Associates, Campbell, California
John R.A. Pearson, Schlumberger Cambridge Research, United Kingdom
Mehran Pooladi-Darvish, University of Calgary, Alberta, Canada
Vladimir E. Romanovsky, University of Alaska, Fairbanks
Terry E. Whitledge, University of Alaska, Fairbanks
Although the reviewers listed above provided many constructive comments and suggestions, they were not asked to endorse the conclusions or recommendations nor did they see the final draft of the report before its release. The review of this report was overseen by Charles G. Groat, University of Texas, Austin, who was appointed by the NRC and was responsible for making certain that an independent examination of this report was carried out in accordance with institutional procedures and that all review comments were carefully considered. Responsibility for the final content of this report rests entirely with the authoring committee and the institution.